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◆ Science Advances2025-10-01· Geochronology

Sub-epsilon natural <sup>234</sup> U/ <sup>238</sup> U measurements refine the <sup>234</sup> U half-life and U-Th geochronology

Hsun‐Ming Hu, Chuan‐Chou Shen, Hai Cheng, Jon Woodhead, R. Lawrence Edwards, Jian‐xin Zhao, Chun‐Yuan Huang, P.-C. Lu, Wei-Yi Chien, Jian Wang, Xuexue Jia, Yūsuke Yokoyama, Yanjun Cai, Jiří Zachariáš

原始摘要(英文原文)· Original abstract
234 U/ 238 U ratios are used across various fields in Earth science, but their measurement is highly challenging due to the four orders of magnitude difference in isotope abundance between 234 U and 238 U. Here, we develop refined techniques for accurately and precisely measuring 234 U/ 238 U using multicollector inductively coupled plasma mass spectrometry, providing a reproducibility of ±0.08 per mil (2σ). At this sub-epsilon precision level, the half-life of 234 U is refined to 245,670 ± 260 years. For U-Th geochronology, systematic uncertainties from decay constants largely cancel, effectively reducing the uncertainty in the 234 U half-life to ~±25 years. This improved measurement precision consequently reduces total 2σ age uncertainties to ±3 thousand years (kyr) at ~600 thousand years ago (ka) and ±6 kyr at ~700 ka, a substantial improvement over earlier methods with uncertainties of tens of thousands of years.
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Sub-epsilon natural <sup>234</sup> U/ <sup>238</sup> U measurements refine the <sup>234</sup> U half-life and U-Th geochronology — 科研速览 Science Skim