Yuan Li, Jingyuan Zhao, Dongtao Liu, Guangshan Zhu
). By precisely regulating monomer structures, catalyst systems, and reaction conditions, key parameters of POPs such as pore size, specific surface area, and surface chemical properties can be directionally designed, thereby obtaining material structures that meet specific application requirements. POPs have been attracting wide attention because of their excellent performances in gas adsorption, gas separation, catalysis, electrochemistry, and many other fields. Moving forward, carbon-carbon coupling reactions have unique potential in expanding the structural diversity of POPs and developing new functional porous materials, representing a promising direction for focused exploration in the field of POP synthesis.