Selective radical defluorinative germylation and hydrogermylation of α-trifluoromethylalkenes

Shuoshuo Zhang, Haibin Xiao, Yanjun Wu, yue zhang, Ling Jin, Junhao Chen, Xiaolei Huang

原始摘要（英文原文）· Original abstract

Photoredox/HAT catalysis enables defluorinative germylation of α-trifluoromethylalkenes with germanes. Organic base ensures selective conversion. Replacing pyridine with DMAP, the reaction encounters a selectivity switch to hydrogermylation.

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Selective radical defluorinative germylation and hydrogermylation of α-trifluoromethylalkenes

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