◆ Chemical communications (Cambridge, England)2026-09-07
Rh-catalyzed asymmetric hydrogenation of silacyclobutanes: a new entry to Si-stereogenic centers.
Xingliang Chen, Yi Du, Mengqing Liu, Xinyu Li, Jiajun Lv, Yuefei Hu, Wenpeng Ma, Wei He, Shuo Chen, Kun An
原始摘要（英文原文）· Original abstract
A Rh-catalyzed asymmetric hydrogenation of silacyclobutanes is disclosed, expanding the concise stereocenter construction from carbon to silicon for the first time. The presence of ortho-substituents around silicon enables the synthesis of diverse tertiary silanes in good yields and with high enantioselectivities (up to 95 : 5 er).