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◆ Chemical communications (Cambridge, England)2026-09-04

Rh(III)-catalyzed (4+2) annulation of 3-aryl-1H-indazoles with allyl alcohol: access to 5,6-dihydroindazolo[3,2-a]isoquinolines.

Tarun Jangir, Krishnan Rangan, Tharmalingam Punniyamurthy, Anil Kumar

原始摘要(英文原文)· Original abstract
A redox-neutral Rh(III)-catalyzed directed (4+2)-annulation of 3-aryl-1H-indazoles with allyl alcohol has been accomplished to furnish 5,6-dihydroindazolo[3,2-a]isoquinolines. The sequential site-selective C-H C-H/N-H annulation, substrate scope and redox-neutral conditions are important practical features.
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Rh(III)-catalyzed (4+2) annulation of 3-aryl-1H-indazoles with allyl alcohol: access to 5,6-dihydroindazolo[3,2-a]isoquinolines. — 科研速览 Science Skim