Cooperative metathesis of H–H/Sn–C <sup>Ar</sup> bonds in stannylene-Ni <sup>0</sup> systems
Jonas Gilch, Philip M. Keil, Mustapha Iddrisu, Tibor Szilvasi, Terrance J. Hadlington
原始摘要(英文原文)· Original abstract
Sn( ii ) and Ni(0) in a stannylene → Ni complex cooperatively activate H 2 , leading to Sn–C/H–H bond metathesis. The formed H-bridged nickela-stannylene is indicative of net reduction at Sn, via a formal oxidative addition/reductive elimination process.