Palladium-Catalyzed Enantioselective Decarboxylative Hydrobenzylation of Allenes with Aryl Acetic Acids
Jian-Bin Lu, Q F Liu, Qian-Qian Yang, Wei Du, Ying‐Chun Chen
原始摘要（英文原文）· Original abstract
We report a palladium-catalyzed asymmetric hydrobenzylation reaction of alkoxy- and amidoallenes with aryl acetic acids by in situ forming labile acetal-type intermediates, and a diverse array of enantioenriched allylic ethers and amides bearing a homobenzylic stereogenic center are finally afforded after decarboxylation.