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◆ Analytical Chemistry2025-11-21· Chemistry

Simultaneous Detection of Hydrogen and Acetylene Using a Photoacoustic Gas Sensor Based on Frequency Tracking and WMS-2 <i>f</i> Technique

Zhiyu Feng, Dajuan Lv, Liangming Xiong, Shiyu Yan, Wenzhe Wang, Lili Peng, Ping Lü, Chaotan Sima

原始摘要(英文原文)· Original abstract
Insulating materials in high-voltage electrical equipment are subject to decomposition during the early stages of faults, with the release of characteristic gases such as hydrogen (H 2 ) and acetylene (C 2 H 2 ). However, the current gas detection methods suffer from issues like cross-sensitivity, compactness, and reliability. This paper proposes a photoacoustic spectroscopy (PAS) gas sensor based on a single DFB laser for the simultaneous detection of H 2 and C 2 H 2 . Specifically, C 2 H 2 serves both as a pump gas for assisting H 2 detection and as the target gas itself. Gas detection is implemented by tracking frequency shift caused by changes in sound velocity and extracting harmonic component generated by infrared absorption. By investigating the attenuation effect of H 2 gas on PA signals, a calibration model is established, correlating C 2 H 2 concentration with the harmonic peak under different H 2 concentrations. Through Allan deviation analysis, the system achieved minimum detection limits (MDLs) of 96 ppm for H 2 at 5.6 s integration time and 0.73 ppb for C 2 H 2 at 894 s. The developed system enables integrated gas analysis in hydrogen-rich environments, showing practical potential for in situ monitoring in power systems.
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Simultaneous Detection of Hydrogen and Acetylene Using a Photoacoustic Gas Sensor Based on Frequency Tracking and WMS-2 <i>f</i> Technique — 科研速览 Science Skim