Silvia González-Rojo, Álvaro Martínez-Sanchez, Xiomar Gómez
The transition to a circular economy requires the safe management of sewage sludge through nutrient and energy recovery. However, pharmaceuticals and personal care products (PPCPs) present a significant challenge. These compounds tend to accumulate in sludge via sorption, shifting the environmental burden from the aqueous phase to the sludge. This manuscript provides a comprehensive review of the scientific literature on technical alternatives for valorizing sewage sludge and removing emerging contaminants. The study evaluates the limitations of conventional biological methods, such as anaerobic digestion and composting, which exhibit variable efficacy and are often insufficient to degrade some commonly used pharmaceuticals. On the contrary, thermal treatments (pyrolysis, gasification, and hydrothermal processes) are considered robust alternatives capable of achieving the high removal of chemical compounds. Furthermore, the article emphasizes the innovative potential of utilizing carbon-based byproducts (biochar and hydrochar) as adsorbents, catalysts, or soil amendment to enhance the removal of PPCPs within the treatment infrastructure itself. The integration of advanced thermal technologies is essential to mitigate the risks of contaminant transfer to the food chain and ensure a safe and sustainable nutrient cycle.