Cristina M. Quintella, Pamela Dias Rodrigues, Jorge Luis Nicoleti, Samira Abdallah Hanna
The transition to a sustainable energy mix is essential to mitigate climate change. Enhanced Oil Recovery (EOR) using low-salinity water (smart water) has emerged as a promising strategy for reducing environmental impacts in the petroleum industry, producing a highly valuable energy source due to both its energy density and market value. This study critically reviews intermediate technological readiness levels (TRL), applying a patent-based approach (TRL 4–5) and a review of articles (TRL 3) to analyze various aspects of smart water for EOR, including its composition. A total of 23 patents from the European Patent Office (Questel Orbit) and 1395 articles from Elsevier’s Scopus database were analyzed, considering annual trends, country distribution, international collaborations, author and applicant affiliations, citation dependencies, and factorial analyses. Both patents and articles show exponential growth; however, international collaboration is more frequent in the scientific literature, while patents remain concentrated in a few countries aligned with their markets. Technologies are focused on wettability, surface complexation, CO2 interactions, emulsification, aerogels, reinjection water treatment, carbonate reservoirs, effluent treatment, nanofluidics, and ASP fluids. Recent topics include CO2 associations, permeability, fractured reservoirs, gels, reservoir water, wettability alteration, and reservoir/oil heterogeneity. The findings indicate the need for multivariated development of customized smart waters to address complex interfacial synergistic mechanisms. International Joint Industry Projects and global regulations on the safe use and composition of hybrid injections are recommended to accelerate development, reduce environmental impacts, and enhance the efficient use of existing fields, alleviating the challenges of finding new reservoirs.