Salik Ahmed, Paolo Sospiro, Michelangelo-Santo Gulino, Maurizio Laschi, Dario Vangi, Daniele Bregoli
Electric vehicles (EVs) represent a key pathway toward reducing greenhouse gas emissions and fossil fuel dependence. Although significant advances have been achieved in energy storage technologies for EVs, a structured comparative assessment that jointly evaluates batteries, supercapacitors, and their hybridisation remains lacking. This review addresses that gap by systematically comparing lithium-ion, lead-acid, and nickel-based batteries with electrochemical double-layer capacitors (EDLCs), pseudocapacitors, and hybrid capacitors across ten performance and sustainability criteria. A literature-informed scoring framework, supplemented by sensitivity analysis under alternative weighting scenarios, is employed to rank the technologies. Particular attention is given to Hybrid Energy Storage Systems (HESS), which combine the high energy density of lithium-ion batteries with the high power density and long cycle life of supercapacitors. The review synthesises evidence that HESS can improve overall energy efficiency by up to 20% and extend battery lifetime by 30–50%, thereby reducing raw-material extraction, electronic waste, and lifecycle cost. Second-life pathways and circular-economy implications are discussed in depth. The findings demonstrate that neither batteries nor supercapacitors alone can satisfy the full spectrum of EV energy demands; instead, their integration within HESS offers the most balanced, sustainable, and economically viable solution. This work provides actionable insights for engineers, policymakers, and stakeholders engaged in next-generation sustainable mobility.