MXene/Cuttlefish-Ink Nanoparticles Incorporated Dual-Purification Sponge for Solar-Driven Oily Wastewater and Microplastic Remediation

The escalating severity of microplastic pollution and oily wastewater discharge has intensified the demand for recyclable, multifunctional, and environmentally benign materials. In this study, we present a composite polyurethane (PU) sponge constructed through the synergistic integration of cuttlefish-ink nanoparticles (CINPs), Ti3C2TX MXene, and polydimethylsiloxane (PDMS). The synergistic CINP@MXene framework imparts high photothermal conversion efficiency and structural stability, while the PDMS coating confers superhydrophobicity. The resulting sponge demonstrates efficient oil absorption and oil–water separation capabilities, alongside a stable photothermal response, achieving a temperature of 84.1 °C within 10 s under 1.5 Sun irradiation. Notably, the sponge absorbed approximately 0.05 g of crude oil within 10 s, the saturated absorption capacity of crude oil under 1.5 solar days was 24.52 g/g, and the adsorption rate of 5 g crude oil within 4 min was 91.4%. Furthermore, it exhibits remarkable adsorption performance toward common microplastics and nanoplastics. Overall, the CINPs@MXene/PU/PDMS sponge represents a versatile and scalable platform with significant potential for addressing challenges in oily wastewater treatment, solar-assisted oil recovery, and microplastic remediation, thereby contributing to sustainable environmental protection efforts.