Junhao Zhou, Yingwu Zhou, Menghuan Guo, Sheng Xiang
The structural application of Fiber-Reinforced Polymers (FRP) is significantly hindered by their inherent thermal sensitivity. This paper presents a comprehensive review of the fire performance of FRP materials and FRP-concrete systems, spanning from material-scale degradation to structural-scale response. Distinct from previous studies, this review explicitly distinguishes between the fire behavior of internally reinforced FRP-reinforced concrete members and externally applied systems, including Externally Bonded Reinforcement (EBR) and Near-Surface Mounted (NSM) techniques. The thermal and mechanical degradation mechanisms of FRP constituents—specifically reinforcing fibers and polymer matrices—are first analyzed, with a focused discussion on the critical role of the glass transition temperature Tg. A detailed comparative analysis of the pros and cons of organic (epoxy-based) and inorganic (cementitious) binders is provided, elaborating on their respective bonding mechanisms and thermal stability under fire conditions. Furthermore, the effectiveness of various fire-protection strategies, such as external insulation systems, is evaluated. Synthesis of existing research indicates that while insulation thickness remains the dominant factor governing the fire survival time of EBR/NSM systems, the irreversible thermal degradation of polymer matrices poses a primary challenge for the post-fire recovery of FRP-reinforced structures. This review identifies critical research gaps and provides practical insights for the fire-safe design of FRP-concrete composite structures.