Chitosan-Templated Synthesis of Fe2O3, NiO, and NiFe2O4 Nanoparticles for Efficient Methylene Blue Dye Removal

Textile production contributes significantly to water pollution, making dye removal crucial for protecting water resources from toxic textile waste. The use of nano-adsorbents for water purification has emerged as a promising approach to removing pollutants from wastewater. Nickel Ferrite (NiFe2O4), Iron Oxide (Fe2O3), and Nickel Oxide (NiO) nanoparticles (NPs) were prepared via an auto-combustion sol–gel technique using chitosan as a capping and stabilizing agent. The prepared nanomaterials were characterized using various techniques such as XRD, UV-Vis DRS, FT-IR, Raman, EDX, SEM, and TEM to confirm their structure, particle size, morphology, functional groups on the surface, and optical properties. Subsequently, the adsorption of the methylene blue (MB) dye using the prepared nanomaterials was studied. NiFe2O4 NPs exhibited the best adsorption behavior compared to the mono-metal oxides. Moreover, all prepared nanomaterials were compatible with the pseudo-second-order model. Further investigations were conducted for NiFe2O4 NPs, showing that both the Freundlich and Langmuir isotherm models can explain the adsorption of the MB dye on the surface of NiFe2O4 NPs. Factors affecting MB dye adsorption were discussed, such as adsorbent dose, concentration of the MB dye, contact time, pH, and temperature. NiFe2O4 NPs exhibited a maximum removal efficiency of the MB dye, reaching 96.8% at pH 8. Different water sources were used to evaluate the ability of NiFe2O4 NPs to purify a wide range of water types.