Nanomaterial-Based SPR Sensing Chip for Detection of Metal Ion Mixtures in Aquatic Environment.

Aquatic heavy metal pollution poses substantial risks to ecological systems and human health, attributable to the toxic properties and bioaccumulative behaviors of metallic ions, including Hg[II], Zn[II], and ion mixtures. A novel SPR sensing chip based on a Ag-BiFeO3-MoS2-graphene hybrid structure is proposed and analyzed for detection of metal ion mixtures. Systematic tuning is implemented for Ag and BiFeO3 film thicknesses to boost the overall sensing capability, aiming to acquire minimized reflectance together with favorable detection sensitivity. Following this step, we investigate how different quantities of MoS2 and graphene layers affect the sensing properties of the SPR biosensor. Analytical outcomes demonstrate that configurations adopting monolayer MoS2 and graphene achieve the maximum phase sensitivity. Moreover, the optimized SPR chip architecture achieves sensing sensitivity two orders of magnitude greater than conventional sensor setups. Numerical investigations are further carried out to evaluate the sensor's response toward various heavy metal ion species. The maximal sensitivity of 1.599 × 106 deg/RIU is realized when detecting Zn[II]. Under this optimal structural setup, the spatial electric field distributions responding to variations in the refractive index of the sensing medium are also characterized. The remarkable sensitivity of the presented sensor configuration makes it a more competitive choice for deployment in further biological detection scenarios.