Effects of Ga and Si Incorporation on Oxygen-Related Defects and Bias-Temperature Stability of ZnSnO Thin-Film Transistors.

Zn-Sn-O (ZTO) thin-film transistors (TFTs) are promising indium-free oxide semiconductor devices, but their electrical stability is limited by oxygen-related defect states. In this study, Ga and Si incorporated ZTO TFTs were systematically compared using an identical bottom-gate top-contact device architecture to investigate dopant-dependent defect modulation and bias-temperature stability. Both Ga and Si incorporation induced a positive threshold-voltage shift and reduced the relative contribution of oxygen-deficient bonding components, suggesting modification of oxygen-related defect environments in the ZTO channel. Optical analysis further showed reduced Urbach energies after dopant incorporation, suggesting a decrease in localized band tail states and reduced structural disorder. Under negative bias temperature stress (NBTS), SZTO exhibited the smallest threshold-voltage shift, demonstrating the most effective stability enhancement. These results indicate that Ga incorporation preserves high field-effect mobility while improving stability, whereas Si incorporation more effectively reduces oxygen-related defect features and provides enhanced NBTS stability. This study provides insight into the dopant-dependent defect engineering for the improved reliability of indium free oxide TFTS.