High-Temperature Performance of Metakaolin-Based Geopolymer Recycled Mortar with Pumice Powder.

This study investigates metakaolin-based geopolymer recycled mortar (GRM) in which recycled fine aggregate (RFA) was volumetrically replaced by pumice powder (PP) at 0% and 60-100%. Ambient compressive and tensile bond strengths were measured, followed by exposure to 600-800 °C for 1-3 h. The evaluation encompassed mass loss ratio, residual mechanical properties, temperature sensitivity, micro-phase evolution, and strength-normalized carbon intensity. Results demonstrated that PP replacement produced a non-monotonic response, governed by the trade-off between improved particle packing and the depletion of the rigid granular skeleton. Among the PP-containing mixtures, PP70 (70% replacement) showed a comparatively favorable mechanical response, with an ambient compressive strength of 31.7 MPa and a mean residual compressive strength of 18.8 MPa (59.3% of its initial value) after exposure to 800 °C for 3 h. Notably, tensile bond strength exhibited greater temperature sensitivity than compressive strength, with deterioration accelerating significantly above 700 °C. SEM and XRD analyses elucidated this macroscopic divergence via a two-stage damage mechanism: while dehydration and matrix contraction dominated at 600 °C, prolonged exposure at 800 °C induced structural rearrangement, with the dominant damage becoming increasingly concentrated at the RFA-matrix interface. Although substituting RFA with processed PP inherently increased the absolute embodied carbon, PP70 exhibited the lowest strength-normalized carbon intensity among the modified mixtures after exposure to 800 °C for 3 h. These findings indicate that, among the investigated high-volume PP mixtures, PP70 provided a comparatively favorable compromise between thermal-mechanical performance and environmental cost.