Effects of Groundwater Flux on Denitrification in a Steep Coastal Agricultural Island in Western Japan Using Push–Pull Tests

This study investigated the influence of groundwater flux and temperature on denitrification in a steep coastal agricultural Island in western Japan. Push–pull tests (PPTs) were conducted at depths of 3 m, 15 m, and 30 m, during winter, spring, and summer to assess denitrification under varying hydrogeological and seasonal conditions. The 3 m layer is silty loam, 15 m is granitic weathered soil, and 30 m is granitic weathered rock, each with distinct hydraulic conductivities and fluxes. The objectives were to assess denitrification rates and fluxes, assess depth- and season-related variability, and determine the relative roles of hydraulic flux and temperature on denitrification. Denitrification was higher at shallow (3 m) and deep (30 m) boreholes during low-flux periods, while low at the intermediate depth (15 m) where fluxes were highest. Temperature variation had weak correlations compared to hydraulic flux, which showed a strong inverse correlation with denitrification. These findings demonstrate that residence time, controlled by groundwater flux, is the dominant factor influencing nitrate attenuation in this steep coastal aquifer. The PPTs results indicate that denitrification rates derived from PPTs decrease under higher hydraulic fluxes, as these conditions promote more oxic conditions. The study highlights the potential for natural denitrification to mitigate nitrate contamination during low-flux periods, providing insights for sustainable groundwater management in agricultural island environments.