Synergistic Removal of Pb(II), Cd(II) and Cr(VI) by Chitosan-Encapsulated Phosphorus-Modified Biochar: Multi-Site Sorption and Immobilization.

Heavy metal pollution has become a global environmental problem. Achieving efficient, stable, and sustainable immobilization of heavy metals by phosphorus (P)-modified biochar remains challenging because of the potential risk of P release. In this study, chitosan-embedded P-modified biochar (CPBC) was produced for the remediation of Pb(II), Cd(II), and Cr(VI). The specific surface area of CPBC was 5.5 times higher than that of the pristine biochar (BC), and the surface was enriched with functional groups such as -OH and -NH3. P-modification facilitated the precipitation of the heavy metals, and chitosan blocked the precipitates inside the biochar. The nature of BC safeguarded the ability to transfer electrons and reduce Cr(VI) to Cr(III), which was further enhanced by the chitosan. Hence, the maximum sorption capacities of CPBC for Pb(II), Cd(II), and Cr(VI) were 29.23%, 129.13%, and 122.12% greater than those of BC. The sequential extraction confirmed that the immobilized Pb(II), Cd(II), and Cr(VI) on CPBC were highly stable, with the sum of acid-soluble and nonbioavailable fractions accounting for 89.14%, 83.73%, and 93.53%, respectively. In addition, chitosan effectively suppressed P release from the P-modified biochar, thereby improving its environmental safety while maintaining excellent heavy metal immobilization performance. The present study demonstrates that CPBC is an effective, environmentally friendly, and universal sorbent to remediate heavy metal pollution in water.