Study on the Influence of Modified Steel Slag Filler on the Rheological Properties and Moisture Stability of Asphalt Mastic

Steel slag is a major solid waste generated by the steelmaking industry. Its characteristics, including high hardness and large specific surface area, offer the potential to replace traditional mineral fillers in asphalt mixtures. However, the high alkalinity of unmodified steel slag often leads to unbalanced rheological properties and insufficient moisture stability in asphalt mastic. In this study, a modified steel slag filler was prepared using a process involving crushing and screening, water washing for dealkalization, and surface modification with a silane coupling agent. Using limestone powder and hydrated lime as control groups, the modification effects on base asphalt mastic were systematically investigated. Rheological properties were characterized using a dynamic shear rheometer (DSR) and bending beam rheometer (BBR). Interfacial performance was evaluated through pull-off tests and water immersion dispersion tests. Furthermore, mechanisms were elucidated using X-ray Fluorescence (XRF), BET specific surface area analysis, and surface free energy (SFE) tests. The results indicate that the modified steel slag significantly enhances the high-temperature deformation resistance of the asphalt mastic. At 58 °C, the complex modulus reached 7.3 MPa, representing increases of 43.3% compared to limestone powder mastic. At −18 °C, the creep stiffness increased by only 3.0%, suggesting that low-temperature cracking resistance remained fundamentally stable. The water immersion dispersion loss rate was 2.12%, and the attenuation rate of pull-off strength after water immersion was 12.5%, indicating that its resistance to moisture damage is superior to that of limestone powder and comparable to that of hydrated lime. Mechanism analysis reveals that the large specific surface area of the modified steel slag strengthens physical adsorption, while the basic oxides undergo a weak acid–base reaction with the acidic components of the asphalt. Additionally, surface modification improves compatibility. The preparation process for modified steel slag is simple; it can be used as a standalone substitute for traditional mineral fillers, balancing both performance and environmental benefits.