Tanja Marković
The aging of wine in oak barrels is a crucial stage in winemaking, greatly influencing its chemical composition, sensory characteristics, and overall quality. Since the Roman Empire, oak barrels have replaced clay amphorae due to their practical and sensory advantages. During barrel aging, interactions between wine, wood, and oxygen improve structure, reduce astringency, develop aromas, and stabilize color. Oak barrels undergo a toasting process that enhances their chemical reactivity and influence on wine. The degree of toasting, which ranges from light to heavy, determines the type and concentration of extractable compounds and shapes the aroma and phenolic profile. Light toasting preserves tannin structure and fruity notes, while heavy toasting releases vanillin, lactones, and caramelized products that contribute to smoky aromas. Factors such as oak species, wood age, processing method, and toasting level all contribute to the final wine profile. This review summarizes the latest findings on the influence of toasting intensity on the chemical composition of red wines, with a focus on aromatic and phenolic compounds and their sensory effects. Extraction mechanisms and their role in defining wine characteristics are also discussed, providing guidance for winemakers to optimize barrel toasting strategies and achieve desired wine styles and qualities.