Yuqi Zheng, Yong Li, Liang Song, Xiaomin Dai
State-of-charge (SOC) estimation for lithium-ion batteries in smartphones is complicated by nonlinear load variation, electro-thermal coupling, aging effects, and heterogeneous user behaviors. This study proposes a multi-physics coupled SOC estimation framework, termed the Multi-Physics Thermo-Electrochemical Coupled SOC Model (MTEC-SOC), to characterize battery behavior under representative user-load conditions within controlled ambient thermal boundaries. The model combines system-level power profiling, thermal evolution, voltage dynamics, and aging-related capacity correction within a unified framework. To support model development and validation, a dual-source dataset is established using laboratory battery characterization data and real-world smartphone behavioral data, from which users are classified into light, heavy, and mixed usage patterns. Comparative results against four benchmark models (M1–M4) show that MTEC-SOC achieves the highest overall accuracy, with average MAE, RMSE, and TTE error values of 0.0091, 0.0118, and 0.08 h, respectively. The results suggest distinct degradation tendencies across user types: calendar aging dominates under prolonged high-voltage dwell in light-use scenarios, whereas, within the tested thermal range, heavy-use scenarios exhibit stronger voltage sag, relative temperature rise, and polarization-related stress; mixed-use scenarios are characterized by transient responses induced by abrupt load switching. Sensitivity analysis further indicates that the predictive behavior of the model is strongly scenario-dependent, with higher-load operation within the calibrated range amplifying parameter perturbations. Overall, the proposed MTEC-SOC framework provides accurate SOC estimation and physically interpretable insight within the evaluated dataset and operating conditions, offering potential guidance for battery management and energy optimization in intelligent mobile terminals.