Thickness-regulated interfacial polarization in CTAB-tailored Bi ₂ WO ₆ for enhanced piezocatalysis

While morphology regulation in conventional catalysis mainly increases the specific surface area to expose more active sites, in piezocatalysis it additionally alters the polarization properties of the materials. In this work, by leveraging the dual benefit of morphology regulation in piezocatalysis, we used cetyltrimethylammonium bromide (CTAB) to synthesize two-dimensional ultrathin Bi2WO6 (BWO) nanosheets, whose minimal thickness of ~ 2.26 nm results from the selective adsorption of CTAB inhibiting molecular layer stacking. This morphological control not only increase the specific surface area more than doubled from 14.47 to 29.15 m2 g‒1, but also enhance the interfacial polarization by 18.34 mV. Consequently, the effective piezoelectric coefficient of the CTAB-modified BWO rose from ~ 10.01 to ~ 27.53 pm V‒1. The modified catalyst, by simultaneously increasing reactive sites and boosting piezoelectric performance, achieves a maximum per-unit-power hydrogen production rate of 61.20 μmol g‒1 h‒1 W‒1, which is one of the highest values ever reported. This work demonstrates a synergistic strategy of morphology engineering to enhance surface reactivity and piezoelectric response, offering a new paradigm for high-performance piezocatalysts.