Danlei Zhu, Yifan Zhou, Xu Wen, Xiangyu Liu, Jiangtao Chan, Jiuyao Du, Jiawei Chen, Shuang Xu, Yuhang Cui, Yuanzhuang Cheng, Wei Jiang, Jianpu Wang, Qihua Xiong, Lian Duan, Jun Yin, Zhaohui Wang, Dongxin Ma
Metal halide perovskite light-emitting diodes (LEDs) are transformative optoelectronic platforms due to their tunable emission, high color purity, and broad color gamut. Nevertheless, the realization of high-luminance blue LEDs, particularly in the deep-blue spectral region, remains challenging compared to their green and red counterparts. This disparity is primarily attributed to the impaired charge transport kinetics and severe nonradiative recombination, both induced by the structural defects in wide-bandgap perovskites. Here, we address this issue through in situ growth of deep-blue–emitting perovskite single-crystal thin films (SCTFs). The resulting SCTFs exhibit exceptional crystallographic orientation, long-range structural ordering, and atomic-level smooth surfaces with a root mean square roughness of 109 picometers. In addition, the SCTFs show a low trap density of 6.9 × 10 14 per cubic centimeter. These structural advantages translate to a high photoluminescence quantum yield of 48% and suppressed nonradiative recombination, enabling deep-blue LEDs with a maximum electroluminescence luminance of 179 candelas per square meter at 419 nanometers.