A Review of the Effects of Supplementary Cementitious Materials on the Autogenous Shrinkage of High-Performance Concrete.

Autogenous shrinkage is a key factor contributing to early-stage cracking in high-performance concrete (HPC), which significantly affects structural durability and service life. As core components of HPC, supplementary cementitious materials (SCMs) can significantly improve concrete workability, mechanical properties, and durability, as well as reduce the risk of shrinkage cracking in HPC, by regulating hydration kinetics, pore structure, and microstructural evolution. The primary objective of this review is to elucidate the differential mechanisms by which different active pozzolanic materials regulate the autogenous shrinkage of HPC. This paper elucidates the patterns and mechanisms by which typical SCMs in HPC (such as fly ash, slag, silica fume, limestone powder, and nano-silica) affect the autogenous shrinkage of HPC. It analyzes the influence of key factors-including the type of SCMs, dosage, particle characteristics, water-to-binder (w/b) ratio, and composite blending on the autogenous shrinkage of HPC. Research indicates that highly reactive SCMs (such as silica fume and nano-silica) accelerate the self-drying process and increase autogenous shrinkage, whereas low-reactivity SCMs (such as fly ash) suppress autogenous shrinkage through dilution effects and by prolonging the hydration cycle. The combined use of multiple SCMs can achieve synergistic control of autogenous shrinkage and mechanical properties. Furthermore, this paper reviews existing autogenous shrinkage prediction models that account for the influence of SCMs and outlines future research directions. At the same time, this review identifies the limitations that currently exist in the research: there is a lack of a unified quantitative theoretical framework for the synergistic effects of multicomponent admixtures. The applicability of prediction models under multi-field coupling of temperature, humidity, and corrosive media is limited. And there is insufficient experimental data on the long-term shrinkage behavior of new low-carbon admixtures such as rice husk ash and calcined clay, which requires further dedicated research.