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◆ Acta crystallographica. Section E, Crystallographic communications2026-09-01

Synthesis and structure of (Z)-2-(eth-oxy-methyl-idene)-2,3,4,9-tetra-hydro-1H-carbazol-1-one.

Makuteswaran Sridharan, Aravazhi Amalan Thiruvalluvar

原始摘要(英文原文)· Original abstract
The title compound, C15H15NO2, crystallizes with two independent mol-ecules (A and B) in the asymmetric unit. One of the methyl-ene C atoms in the cyclo-hexene ring in mol-ecule A was refined as disordered over two sites in a 0.818 (5) to 0.182 (5) ratio. In the crystal, pairwise N-H⋯O hydrogen bonds generate centrosymmetric A + A and B + B dimers characterized by R 2 2(10) loops and the dimers are linked by A + B and B + A C-H⋯O and C-H⋯π inter-actions. Aromatic π-π stacking inter-actions are also present and together, the inter-molecular inter-actions generate a three-dimensional network.
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Synthesis and structure of (Z)-2-(eth-oxy-methyl-idene)-2,3,4,9-tetra-hydro-1H-carbazol-1-one. — 科研速览 Science Skim