Spin-to-Charge Conversion Driven by Inverse Chiral-Induced Spin Selectivity.

Chiral molecules have attracted significant multidisciplinary interest and extensive research owing to their remarkable ability to achieve charge-to-spin conversion, known as the chiral-induced spin selectivity (CISS). A recent experiment has revealed that chiral molecules also exhibit an unexpected capability for spin-to-charge conversion, referred to as the inverse CISS (ICISS), opening unprecedented avenues for the study and application of chiral molecules. Here, we propose a theoretical model, suggesting that ICISS can be understood in terms of spin-dependent electron deflection induced by the interplay between spin and chiral structure. Our numerical results are consistent with experimental observations, demonstrating that ICISS persists under strong disorder. Our model also reproduces the inverse spin Hall effect (ISHE) in this experiment. Comparative analysis indicates that ICISS exhibits a spin-to-charge conversion behavior that differs from ISHE. Our Letter develops a microscopic theoretical model that accounts for the experimentally observed phenomena, and may provide a useful perspective for organic spintronics.