Chao Liang, Ce Yang, Wei Huang, Li You
Rydberg atoms, with their large transition dipole moments and extreme sensitivity to electric fields, have attracted widespread attention as promising candidates for next-generation quantum precision electrometry. Meanwhile, exceptional points (EPs) in non-Hermitian systems have opened new avenues for ultrasensitive metrology. Despite increasing interest in non-Hermitian physics, EP-enhanced sensitivity has rarely been explored in Rydberg atomic platforms. Here, we provide a new theoretical understanding of Autler-Townes effect-based Rydberg electrometry under non-Hermitian conditions, showing that dissipation fundamentally modifies the spectral response and enables sensitivity enhancement via EP-induced nonlinearity. Experimentally, we realize a second-order EP in a passive thermal Rydberg system without requiring gain media or cryogenics, and demonstrate the first EP-enhanced atomic electrometer. The EP can be tuned in real time by adjusting laser and microwave parameters, forming a flexible and scalable platform. Near the EP, the system exhibits a square-root response, yielding a nearly 20-fold enhancement in responsivity. Using amplitude-based detection, we achieve a sensitivity of 22.68(3) nV cm^{-1} Hz^{-1/2} under realistic conditions. Our Letter establishes a practical, tunable platform for EP-enhanced sensing and real-time control, with broad implications for quantum metrology in open systems.