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◆ Physical review. B./Physical review. B2026-02-24· Condensed matter physics

Stabilizing and tuning superconductivity in <mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML"> <mml:mrow> <mml:msub> <mml:mi>La</mml:mi> <mml:mn>3</mml:mn> </mml:msub> <mml:msub> <mml:mi>Ni</mml:mi> <mml:mn>2</mml:mn> </mml:msub> <mml:msub> <mml:mi mathvariant="normal">O</mml:mi> <mml:mrow> <mml:mn>7</mml:mn> <mml:mtext>−</mml:mtext> <mml:mi>δ</mml:mi> </mml:mrow> </mml:msub> </mml:mrow> </mml:math> films: Oxygen recycling protocol reveals hole-doping analogue

Lifen Xiang, Siyi Lei, Xiaolin Ren, Ziao Han, Zijian Xu, X. J. Zhou, Zhihai Zhu

原始摘要(英文原文)· Original abstract
The recent achievement of superconductivity in La$_3$Ni$_2$O$_{7-δ}$ with transition temperatures exceeding 40 K in thin films under compressive strain and 80 K in bulk crystals under high pressure opens new avenues for research on high-temperature superconductivity. The realization of superconductivity in thin films requires delicate control of growth conditions, which presents significant challenges in the synthesis process. Furthermore, the stability of superconducting La$_3$Ni$_2$O$_{7-δ}$ films is compromised by oxygen loss, which complicates their characterization. We introduce an effective recycling protocol that involves oxygen removal in a precursor phase followed by ozone-assisted annealing, which restores superconducting properties. By tuning the oxygen content, we construct an electronic phase diagram that highlights oxygen addition as a potential analogue to hole doping via La substitution with Sr, providing insights into the doping mechanism and guiding future material optimization.
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Stabilizing and tuning superconductivity in <mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML"> <mml:mrow> <mml:msub> <mml:mi>La</mml:mi> <mml:mn>3</mml:mn> </mml:msub> <mml:msub> <mml:mi>Ni</mml:mi> <mml:mn>2</mml:mn> </mml:msub> <mml:msub> <mml:mi mathvariant="normal">O</mml:mi> <mml:mrow> <mml:mn>7</mml:mn> <mml:mtext>−</mml:mtext> <mml:mi>δ</mml:mi> </mml:mrow> </mml:msub> </mml:mrow> </mml:math> films: Oxygen recycling protocol reveals hole-doping analogue — 科研速览 Science Skim