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◆ Chemistry Letters2026-03-01· Photodegradation

Influence of oxygen vacancy in CaCu3Ti4O12 materials on photocatalytic degradation of methylene blue dye pollutants

cuncun 中国 Kong, Pengfei Cheng, xueyan 中国 Su, Qin Xinrui, Xin Liu, Jiale Wang, Yue Wang

原始摘要(英文原文)· Original abstract
Abstract Oxygen vacancies were introduced into CaCu3Ti4O12 using bisphenol A to enhance its UV-driven photodegradation of methylene blue. Structural and spectroscopic analyses confirmed successful vacancy formation. Radical trapping identified ·OH as a key species. Optimized samples achieved 84.68% removal (0.0061 min−1), far exceeding pristine CaCu3Ti4O12 (32.78%), via oxygen vacancies. This work provides a new route to optimize photodegradation performance of CaCu3Ti4O12 by the modulation of intrinsic point defect structure.
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Influence of oxygen vacancy in CaCu3Ti4O12 materials on photocatalytic degradation of methylene blue dye pollutants — 科研速览 Science Skim