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◆ Journal of Materials Chemistry A2026-01-01· Chemistry

A 4,4-connected 2D POM-based complex with synergistic mixed-valence Cu <sup>I</sup> /Cu <sup>II</sup> for mild and efficient catalytic oxidation of phenols

Jiayu Sun, Si-Yu Sun, Zhong Zhang, Mei-tong Li, Guo-Cheng Liu, Xiu-Li Wang

原始摘要(英文原文)· Original abstract
A 4,4-connected 2D POM-based complex incorporating mixed-valence copper centers was successfully synthesized, exhibiting high-performance oxidation of 2,3,6-TMP to TMBQ with 98% conversion and >99% selectivity in 13 minutes at 50 °C.
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A 4,4-connected 2D POM-based complex with synergistic mixed-valence Cu <sup>I</sup> /Cu <sup>II</sup> for mild and efficient catalytic oxidation of phenols — 科研速览 Science Skim