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◆ Chemical Science2026-01-01· Allylic rearrangement

Photoinduced deacylative epoxidation of ketone derivatives with allylic peroxides

Jiangtao Lin, Mingqian Zhou, Ziyang Li, Jiang Duan, Xiaoyu Liu, Y P Wang, Chao Shu

原始摘要(英文原文)· Original abstract
the photoinduced radical cyclization of ketone-derived pro-aromatic dihydroquinazolinones. This system operates under very mild conditions and showcases a broad substrate scope with excellent functional group tolerance (over 50 examples). Its gram-scale preparation and late-stage transformations emphasize its potential in drug discovery. A possible mechanism has been proposed based on mechanistic studies.
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Photoinduced deacylative epoxidation of ketone derivatives with allylic peroxides — 科研速览 Science Skim