Alkyl bromide-promoted photo-methylation of benzaldehydes with DMSO as the methyl source.
Alexander Yu Smirnov, Svetlana A Krasnova, Victoria E Opryshko, Andrey A Mikhaylov, Mikhail S Baranov, Dmitrii S Ivanov
原始摘要(英文原文)· Original abstract
Alkyl bromide-promoted photocatalyst-free methylation of benzaldehydes with DMSO as the methyl source and solvent is investigated. Mechanistic studies support the origin of methyl from DMSO via a Fenton-like process. Bromo or 2-alkoxy groups enhance the reaction efficiency.