◆ Chemical communications (Cambridge, England)2026-09-09
Zn metalation of porphyrinic covalent organic polymers enables selective photocatalytic CO2 reduction to CH4.
Qing Li, Yao Zhong, Jiaxin Wang, DanDan Lin, Yuting Xiao, Xiaowei Che, Shiqi Tong, Renjie Song
原始摘要（英文原文）· Original abstract
Metal-centre-engineered porphyrinic covalent organic polymers were developed for CO2 photoreduction. ZnTP-BTD exhibited superior light harvesting, CO2 uptake and charge separation, achieving a CH4 evolution rate of 154.8 μmol h-1 with 87% selectivity.