◆ Chemical communications (Cambridge, England)2026-08-13
Ti-phosphine oxide frameworks with oxygen vacancies for light-enhanced cycloaddition of CO2 with epoxides.
Zhen Wu, Nan Jiang, Yunqian Zhang, Qingmei Ge, Yin-Hui Huang, Hang Cong, Wenfeng Zhao, Xi-Sheng Wang
原始摘要（英文原文）· Original abstract
A Ti-based phosphine oxide coordination material (Ti-BCPPO) featuring PO-Ti secondary coordination and oxygen vacancies promotes visible-light absorption and charge separation, enabling efficient CO2 cycloaddition with epoxides to cyclic carbonates under mild conditions with up to 99% yield.