Hidden in plain sight: commonly used copper N-heterocyclic carbene catalysts gain stabilization from anagostic Cu⋯H–C interactions
Connly Yan, Tieyan Chang, Yu-Sheng Chen, Alexander L Paterson, Dan McElheny, Neal Mankad
原始摘要（英文原文）· Original abstract
= 1.09 ± 0.01 for the hydrosilylation of a ketone at 315 K. Since these anagostic interactions were not previously assigned apart from selected supramolecular systems, knowledge of anagostic stabilization of Cu-NHC complexes is expected to guide future catalyst designs.