Radical docking–migration: a powerful strategy for difunctionalization of alkenes and alkynes

radical addition and migration cascades. The scope encompasses various migrating groups, including aryl, heteroaryl, alkynyl, oximino, alkenyl, and imino units, and highlights extensions to challenging unactivated alkenes and alkynes. The mechanistic insights, substrate scope, and synthetic applications of these transformations are discussed, underscoring the potential of the radical docking-migration strategy in modern synthetic chemistry.