A hydrogen-bonded organic framework possessing one-dimensional wide channels surrounded by the naphthalenediimide plane

. Slip-stacking of a hydrogen-bonded two-dimensional network composed of tetracarboxylic acid NDITA with an NDI core provides both electron-conductive π-stacked NDI domains and pore channels surrounded by the NDI surface. Since aromatic solvents can come into contact with the NDI moieties in the pores, the HOF exhibits solvent-dependent photophysical behaviors. In particular, inclusion of dimethoxybenzene (DMB) into the pores enhances charge-transfer interactions, resulting in significant changes in absorption and emission spectra as well as electron conductivity.