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◆ Nanoscale Advances2025-11-05· Quantum dot

Biomass-derived surface-functionalized graphene quantum dots for aggregation-induced green fluorescence

Syed Adil Shah, Eman Gul, Syed Niaz Ali Shah

原始摘要(英文原文)· Original abstract
3 nm) were synthesized from biomass extracts and subsequently surface functionalized to enhance their properties. Interestingly, the functionalization process not only introduced inner defects but also promoted the aggregation of GQDs, which, in turn, led to a significant boost of green fluorescence. The successful synthesis of GQDs and the incorporation of functional groups were confirmed using various characterization techniques. UV-vis spectroscopy was employed to identify the characteristic optical signatures of GQDs, while FTIR spectroscopy verified the presence of specific functional groups. Dark-field scanning transmission electron microscopy (STEM) was utilized for size authentication, visualization of inner defects, and insights into the morphological features of the GQDs. X-ray photoelectron spectroscopy was employed for elemental analysis. Additionally, luminescence studies, including fluorescence and photoluminescence, were conducted to investigate the optical properties. The meticulously prepared surface-functionalized GQDs, showcasing elevated luminescence, hold significant promise as advanced multifunctional materials. Their semiconducting nature makes them strong candidates for high-performance display applications, while their exceptional biocompatibility and robust fluorescence position them as an ideal platform for drug delivery, particularly in cancer therapeutics.
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