Constructing highly reactive Pd nanoparticles with π bonds in imidazolium-based metal–organic frameworks for chemoselective CO 2 multicomponent transformation

Jie Chen, Lingfang Kong, Qinggang Zhang, Wenjing Shi, Shiyong Zhang, Hongen Qu, Guohai Xu, Zhonggao Zhou, Yiwang Chen

原始摘要（英文原文）· Original abstract

A scalable π-bond-stabilized 10%Pd@Er-MOF catalyst drives 100% selective 4C-TCRs of propargylic amines, aryl iodides, and in situ -activated CO 2 , yielding oxazolidinones with 99% yield and 227 h −1 TOF.

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Constructing highly reactive Pd nanoparticles with π bonds in imidazolium-based metal–organic frameworks for chemoselective CO <sub>2</sub> multicomponent transformation

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