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◆ Dalton Transactions2025-12-29· Planar

[S©Cd <sub>5</sub> S <sub>5</sub> ] <sup>2−</sup> : a planar pentacoordinate sulfur dianion stabilized by a transition-metal framework

Xin-Bo Liu, Yu-le Dou, xiao-han yin, Lijuan Cui, Zhong-hua Cui

原始摘要(英文原文)· Original abstract
A novel planar pentacoordinate sulfur (ppS) species with a starlike D 5h symmetry is identified in the Cd 5 S 6 2− cluster. The rare planar hypercoordinate system is stabilized mainly by electrostatic interactions arising from Cd → S charge transfer.
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[S©Cd <sub>5</sub> S <sub>5</sub> ] <sup>2−</sup> : a planar pentacoordinate sulfur dianion stabilized by a transition-metal framework — 科研速览 Science Skim