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◆ Chemical Communications2026-01-01· Cationic polymerization

Synthesis of sulfur- and oxygen-bridged cationic [4]-helicenes mediated by Friedel–Crafts-S <sub>N</sub> Ar tandem reactions for red-light-driven organophotoredox catalysis

Ryoga Hasebe, R. Hanada, Yuta Tanaka, Yuta Goto, Mio Takeuchi, Hiroyoshi Takamura, Isao Kadota, Kenta Tanaka, Yujiro Hoshino

原始摘要(英文原文)· Original abstract
Ar reaction of a diaryl sulfide or a diaryl ether with a (thio)salicylic acid has been developed. The sulfur-bridged cationic [4]-helicenes are suitable as catalysts for photoredox reactions under low-energy light sources such as red LED light.
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Synthesis of sulfur- and oxygen-bridged cationic [4]-helicenes mediated by Friedel–Crafts-S <sub>N</sub> Ar tandem reactions for red-light-driven organophotoredox catalysis — 科研速览 Science Skim