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◆ Chemical Communications2025-11-26· Materials science

Reversible twisting-induced crystalline–polycrystalline transformation in cyanoacrylate crystals

Thiyagaraj Parthasarathy, Aritra Bhowmik, Biswajit Bhattacharya, Manish Kumar Mishra, Soumyajit Ghosh

原始摘要(英文原文)· Original abstract
We report cyanoacrylate-based organic crystalline materials that exhibit reversible hand-induced helical twisting through the combined action of 1D elasticity and 2D plasticity. These crystals twist and untwist without lattice damage, retaining their elastic integrity through π slip-stacking and Cl⋯Cl, C-H⋯Cl, and Me⋯Me interactions. Their unique integration of elastic recovery, plastic bending, and reversible twisting highlights their potential as mechanically adaptive materials for flexible and responsive devices.
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Reversible twisting-induced crystalline–polycrystalline transformation in cyanoacrylate crystals — 科研速览 Science Skim