Persistent spin textures, altermagnetism and charge-to-spin conversion in metallic chiral crystals TM3X6

Abstract Chiral crystals, due to the lack of inversion and mirror symmetries, exhibit unique spin responses to external fields, enabling physical effects rarely observed in high-symmetry systems. Here, we show that materials from the chiral dichalcogenide family TM 3 X 6 (T = 3d, M = 4d/5d, X = S) exhibit persistent spin texture (PST) – unidirectional spin polarization of states across large regions of the reciprocal space – in their nonmagnetic metallic phase. Using the example of NiTa 3 S 6 and NiNb 3 S 6 , we show that PSTs cover the full Fermi surface, a rare and desirable feature that enables efficient charge-to-spin conversion and suggests long spin lifetimes and coherent spin transport above magnetic ordering temperatures. At low temperatures, the materials that order antiferromagnetically become chiral altermagnets, where spin textures originating from spin-orbit coupling and altermagnetism combine in a way that sensitively depends on the orientation of the Néel vector. Using symmetry analysis and first-principles calculations, we classify magnetic ground states across the family, identify cases with weak ferromagnetism, and track the evolution of spin textures and charge-to-spin conversion across magnetic phases and different Néel vector orientations, revealing spin transport signatures that allow one to distinguish Néel vector directions. These findings establish TM 3 X 6 as a tunable platform for efficient charge-to-spin conversion and spin transport, combining structural chirality, persistent spin textures, and altermagnetism.