Ikechukwu David Nwosu, Lujo Matasovic, Tárcius N. Ramos, Nguyen Le Phuoc, Giacomo Londi, Alexander J. Gillett, Daniel T. W. Toolan, Charles Smith, George F. S. Whitehead, Mireille Blanchard-Desce, Jonathan Daniel, Mikko Linnolahti, Yoann Olivier, Alexander S. Romanov
Abstract Advanced photonic materials showing two-photon absorption (2PA) have been widely explored to develop three-dimensional imaging, micro and nanofabrication, all-optical switching, lithography on a nanoscale and many other enabling technologies. These all require nonlinear absorption chromophores with intrinsic 2PA cross-sections and long-term photo- and thermal stability. Here, we disclose the very first example of the dipolar carbene-metal-amide (CMA) material showing a enhanced 2PA cross-section up to 105 GM. Overall molecular design considerations such as extended π-conjugation (to increase polarizability), minimizing the singlet-triplet energy gap (ΔE ST ), and using heavy metal atoms are the first design principles to obtain bright one- and two-photon excited thermally activated delayed fluorescence (TADF) material, showing one of the highest radiative rate of 2.18·10 6 s -1 across CMA materials. Bright red CMA 2P-TADF material shows excellent photostability (LT 50 = 3 h) to 20 mW femtosecond pulsed laser excitation at 1000 nm, encouraging further CMA exploration for future applications in advanced photonic technologies requiring third-order nonlinear optical properties.