Charting the influence of deuterium sources in hydrogen isotope exchange using a cobalt(III) catalytic platform
Sergio Barranco, Inbal L. Eshel, Jiayu Zhang, Marco Di Matteo, Anat Milo, Mónica H. Pérez‐Temprano
原始摘要(英文原文)· Original abstract
Directed hydrogen exchange is one of the main strategies for accessing isotopically labelled organic scaffolds, but the rationale for deuterium source selection has not been fully explored yet. Now the authors reveal the influence of the deuterium source in base-assisted site-selective C–H deuteration reactions across substrates in cobalt catalysis.