Jae Hyun Kim, Hyojeong Choi, Kenjiro Fukuda, Jaebin Jeong, Jun‐Gyu Choi, Sunghoon Lee, Tomoyuki Yokota, Sang Min Won, Joohoon Kang, Yei Hwan Jung, Jongin Hong, Seulki Song, Takao Someya, Hyeok Kim, Sungjun Park
Near-infrared (NIR) organic photodetectors (OPDs) offer a promising platform for skin-integrated optical communication systems, but achieving high-speed operation under mechanical stress remains a central obstacle. Here, we report a skin-conformable OPD with a 3 μm total thickness that achieves a specific detectivity calculated from noise-equivalent power of 0.84 × 1014 Jones at 790 nm and a − 3 dB cut-off frequency exceeding 1 MHz, maintained under 66% compressive strain and sub-5 μm bending radius. This performance is enabled by an engineered Br-functionalized PACz hole transport layer, which facilitates efficient charge extraction without compromising mechanical resilience. When conformally mounted on human skin, the device supports angle-independent responsivity across a 0–90° range and enables wireless reception of audio-modulated signals from a 100 m distant source with a bit-error rate of 10−3. These results define a new performance regime for ultrathin, deformable NIR photodetectors by overcoming the trade-off between speed and flexibility, and demonstrate their scalable integration into skin-mounted, interactive communication systems. The authors developed a highly sensitive skin-conformal NIR organic photodetector with fast photoresponse speed that achieves MHz-speed, angle-free, and long-range (100 m) wireless optical communication with stable performance under mechanical deformation.