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◆ Journal of the American Chemical Society2026-03-25· Chemistry

Exploring Spin-State Selective Harvesting Pathways from Singlet Fission Dimers to a Near-Infrared-Emissive Spin-Flip Emitter

Percy Gonzalo Sifuentes-Samanamud, Adrian Sauer, Aki Masaoka, Yuta Sawada, Yuya Watanabe, Ilias Papadopoulos, Katja Heinze, Yōichi Sasaki, Nobuo Kimizuka

原始摘要(英文原文)· Original abstract
-terphenylene bridging units were quantified to be 112 ± 6%, 132 ± 2%, and 128 ± 4%, respectively, in solution. The drop of fluorescence lifetimes of the SF dimers at high concentrations of the molybdenum complex implies energy transfer from exchange-coupled triplet pairs, highlighting the importance of controlling exchange interaction and triplet pair recombination. This work represents a significant step toward developing exciton/photon amplification materials by combining SF materials with transition-metal complexes, advancing the application of SF beyond conventional limitations.
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Exploring Spin-State Selective Harvesting Pathways from Singlet Fission Dimers to a Near-Infrared-Emissive Spin-Flip Emitter — 科研速览 Science Skim