John D. Ponis, Kenna Ashen, S. Chakraborty, George Agbeworvi, Michelle A. Smeaton, Chengdong Wang, A.M. Jessel, Douglas H. Fabini, Fanni Jurànyi, D. L. Quintero-Castro, Nick A. Shepelin, Dariusz Jakub Gawryluk, Katherine Jungjohann, Shruti Hariyani, Xiaofeng Qian, Sarbajit Banerjee
The results illustrate the use of topochemical ion insertion to modulate stacking relationships and magnetic transition characteristics.
High Resolution Image Download MS PowerPoint Slide Low-dimensional materials manifest structural anisotropy, quantum confinement, and tightly bound excitonic states, which make them attractive building blocks that can be assembled within three-dimensional laterally stitched heterostructures, stacked van der Waals solids, and complex moiré superlattices. Ion intercalation in the galleries between layered materials provides a means of modifying interlayer separation and coupling, but it is also known to drive the shearing of the layers. In this article, we explore the distinct ligand coordination environments afforded by vanadyl oxygens of singular [V 4 O 10 ] sheets and examine how the size, polarizability, and stoichiometry of Group I cations sandwiched between such layers determine the interlocking of the sheets in stacked structures. Based on the topochemical insertion of alkali-metal ions into the layered λ-V 2 O 5, we identify seven types of guest ion coordination sites discretized into four distinct regimes of interlayer shear in units of half octahedral widths. The coordination preferences of intercalated cations govern how they interlock 2D [V 4 O 10 ] sheets and engender specific shear conformations. We present evidence that static and dynamic disorder in guest ion arrangement modulate the magnetic structure of the intercalated compounds based on electrostatic polarization, localization of charge and spin density, and lattice distortion. The results illustrate the use of topochemical ion insertion to modulate stacking relationships and magnetic transition characteristics.