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◆ ACS Omega2026-01-22· Adsorption

Physical and Chemical Characterization, Adsorption Kinetics, Thermodynamic Analysis, and the Mechanism Involved in the Removal of Methylene Blue Dye by a Biosorbent from Pecan Nutshells

Lucas Mironuk Frescura, Rogério V. Lourega, Nicole W. da Silva, Marcelo Barcellos da Rosa

原始摘要(英文原文)· Original abstract
) indicate that the adsorption process is spontaneous and endothermic, with an enthalpy change characteristic of weak to moderate interactions. Kinetic data were best described by the pseudo-second-order model, with equilibrium reached within approximately 180 min. Intraparticle diffusion analysis revealed a multistep adsorption involving an initial boundary-layer diffusion followed by a slower pore diffusion. Overall, the adsorption mechanism is interpreted as multifactorial, governed by hydrogen bonding, π-π stacking, and van der Waals forces, consistent with a physisorption-dominated process strengthened by structural heterogeneity. These results demonstrate that PNS combines high capacity with operational simplicity, representing a scalable and sustainable alternative for the treatment of dye-contaminated wastewater.
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Physical and Chemical Characterization, Adsorption Kinetics, Thermodynamic Analysis, and the Mechanism Involved in the Removal of Methylene Blue Dye by a Biosorbent from Pecan Nutshells — 科研速览 Science Skim